Sulfonation of Bamboo Fiber and Thermoplasticity of Its Modified Products Based on Different Pretreatments

Peng Bo; Shi Chun; Shi Zhengjun; Yang Jing; Yang Haiyan; Deng Jia

doi:10.11929/j.swfu.202101053

Journal of Southwest Forestry University > 2022 > 42(2): 111-119. > DOI: 10.11929/j.swfu.202101053

Peng Bo, Shi Chun, Shi Zhengjun, Yang Jing, Yang Haiyan, Deng Jia. Sulfonation of Bamboo Fiber and Thermoplasticity of Its Modified Products Based on Different Pretreatments[J]. Journal of Southwest Forestry University, 2022, 42(2): 111-119. DOI: 10.11929/j.swfu.202101053

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Sulfonation of Bamboo Fiber and Thermoplasticity of Its Modified Products Based on Different Pretreatments

1.
Key Laboratory of State Forestry and Grassland Administration on Highly-efficient Utilization of Forestry Biomass Resources in Southwest China, College of Chemical Engineering, Southwest Forestry University, Kunming Yunnan 650233, China
2.
Key Laboratory of Ministry of Education on Forestry Resources Conservation and Use in Southwest Mountains of China, College of Forestry, Southwest Forestry University, Kunming Yunnan 650233, China

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Received Date: January 20, 2021
Revised Date: March 17, 2021
Available Online: April 25, 2021
Published Date: March 19, 2022

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Abstract

Abstract

Alkali pretreatment, hydrothermal pretreatment, and H₂O₂ pretreatment was developed to pretreat the Dendrocalamus sinicus, which is the largest bamboo species distributed in Southwest China. The objective of the present research was to evaluate the effect of pretreatments on the accessibility and thermoplasticity of bamboo fiber during sulfonation modification. It was demonstrated that 3 pretreatments could obviously improve the accessibility of sulfonation reaction, and a maximum of 0.49 mmol/g was achieved as the bamboo powder was pretreated with H₂O₂ which had the highest degree of sulfonation modification. In addition, the plasticity of bamboo fiber was improved with the increase of sulfonic group content after sulfonation. The DSC analysis results revealed that the thermoplasticity of bamboo fiber was significantly improved under the synergistic effect of H₂O₂ pretreatment combined with sulfonation modification, and its glass transition temperature (T_g) was 104.71 ℃.
- bamboo fiber,
- pretreatment,
- sulfonation,
- thermoplasticity

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References

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