| Citation: |
Zhang Wen-bin, Liu Cheng-yuan, Du Zhi-yuan, Lei Hong, Zhou Xiao-jian, Cao Ming. Preparation and performance study of lignin-citric acid adhesive[J]. Journal of Southwest Forestry University. DOI: 10.11929/j.swfu.202405058
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Sodium lignosulfonate(SL) and citric acid(CA) were utilized as raw materials for the production of an all-biomass wood adhesive called lignin-citric acid(SCA) adhesive. The adhesive's structural characteristics were examined using X-ray photoelectron spectroscopy(XPS) and Fourier transform infrared spectroscopy(FT-IR), while its curing properties were evaluated through differential scanning calorimetry(DSC) and dynamic thermomechanical analysis(DMA). Additionally, the optimal preparation process for the SCA adhesive was determined by varying the process conditions, such as the CA/SL mass ratio, hot pressing temperature, and hot pressing time. The experimental results revealed that the hydroxyl group in SL and the carboxyl group in CA underwent an esterification reaction, resulting in the formation of a new ester bond. Furthermore, the lignin-citric acid adhesive demonstrated good bonding properties and water resistance when the CA/SL mass ratio was 1.25/1. The plywood prepared using SCA5 adhesive exhibited satisfactory dry bonding strength, as well as 24-hour bonding strength and water resistance when pressed at a pressure of 1.0 MPa, temperature of 220 °C, and time of 3 minutes. Specifically, the SCA5 adhesive achieved dry bonding strength, 24-hour wet bonding strength in cold water, 63 °C wet bondinging strength in hot water, and 93 °C wet bonding strength in boiling water of 0.84 MPa, 1.15 MPa, 0.98 MPa, and 0.78 MPa, respectively. These bonding strengths met the requirements for Class II plywood according to GB/T 9846—2015 standards, which provides reference for the high value utilization of lignin and citric acid.
| [1] |
李露霏, 张忠涛. 无醛人造板产业现状及展望 [J]. 中国人造板, 2023, 30(10): 8−12.
|
| [2] |
何明明, 王雅慧, 刘真, 等. 我国生物质人造板产业资源利用与发展前景 [J]. 林产工业, 2023, 60(3): 84−87.
|
| [3] |
王慧珊, 吕少一, 彭立民. 人造板用无机胶黏剂研究现状 [J]. 林产工业, 2023, 60(6): 64−69.
|
| [4] |
Wang J L, Guo Y J, Long G D, et al. Integrated sensing layer of bacterial cellulose and polyethyleneimine to achieve high sensitivity of ST-cut quartz surface acoustic wave formaldehyde gas sensor [J]. Journal of Hazardous Materials, 2020, 388: 121743. DOI: 10.1016/j.jhazmat.2019.121743
|
| [5] |
Sandhya P K, Sreekala M S, Padmanabhan M, et al. Effect of starch reduced graphene oxide on thermal and mechanical properties of phenol formaldehyde resin nanocomposites [J]. Composites Part B: Engineering, 2019, 167: 83−92. DOI: 10.1016/j.compositesb.2018.12.009
|
| [6] |
Liu Z, Liu T, Li Y, et al. Performance of soybean protein adhesive cross-linked by lignin and cuprum [J]. Journal of Cleaner Production, 2022, 366: 132906. DOI: 10.1016/j.jclepro.2022.132906
|
| [7] |
Dodangeh F, Seyed Dorraji M S, Rasoulifard M H, et al. Synthesis and characterization of alkoxy silane modified polyurethane wood adhesive based on epoxidized soybean oil polyester polyol [J]. Composites Part B: Engineering, 2020, 187: 107857. DOI: 10.1016/j.compositesb.2020.107857
|
| [8] |
Jiang W, Kumar A, Adamopoulos S. Liquefaction of lignocellulosic materials and its applications in wood adhesives—a review [J]. Industrial Crops and Products, 2018, 124: 325−342. DOI: 10.1016/j.indcrop.2018.07.053
|
| [9] |
Lei Z H, Jiang K, Chen Y Z, et al. Study on the bonding performance and mildew resistance of soy protein-based adhesives enhanced by hydroxymethyl l-tyrosine cross-linker [J]. International Journal of Adhesion and Adhesives, 2022, 117: 103167. DOI: 10.1016/j.ijadhadh.2022.103167
|
| [10] |
Penniston K L, Nakada S Y, Holmes R P, et al. Quantitative assessment of citric acid in lemon juice, lime juice, and commercially-available fruit juice products [J]. Journal of Endourology, 2008, 22(3): 567−570. DOI: 10.1089/end.2007.0304
|
| [11] |
Cumming M H, Leonard A R, LeCorre-Bordes D S, et al. Intra-fibrillar citric acid crosslinking of marine collagen electrospun nanofibres [J]. International Journal of Biological Macromolecules, 2018, 114: 874−881. DOI: 10.1016/j.ijbiomac.2018.03.180
|
| [12] |
Reddy N, Li Y, Yang Y Q. Alkali-catalyzed low temperature wet crosslinking of plant proteins using carboxylic acids [J]. Biotechnology Progress, 2009, 25(1): 139−146. DOI: 10.1002/btpr.86
|
| [13] |
Cahyono T D, Syahidah. Citric acid, an environmentally friendly adhesive and wood impregnation material-review of research [J]. IOP Conference Series: Materials Science and Engineering, 2019, 593(1): 012009. DOI: 10.1088/1757-899X/593/1/012009
|
| [14] |
Šefc B, Trajković J, Sinković T, et al. Compression strength of fir and beech wood modified by citric acid [J]. Drvna Industrija, 2012, 63(1): 45−50. DOI: 10.5552/drind.2012.1123
|
| [15] |
Dong Y M, Xue Q X, Fu Z Y, et al. Enhancing wood stability and fire retardancy through citric acid and phosphorylated sucrose stearate cross-linking modification [J]. Construction and Building Materials, 2023, 393: 131946. DOI: 10.1016/j.conbuildmat.2023.131946
|
| [16] |
Umemura K, Ueda T, Kawai S. Characterization of wood-based molding bonded with citric acid [J]. Journal of Wood Science, 2012, 58(1): 38−45. DOI: 10.1007/s10086-011-1214-x
|
| [17] |
Del Menezzi C, Amirou S, Pizzi A, et al. Reactions with wood carbohydrates and lignin of citric acid as a bond promoter of wood veneer panels [J]. Polymers, 2018, 10(8): 833. DOI: 10.3390/polym10080833
|
| [18] |
Kusumah S S, Arinana A, Hadi Y S, et al. Utilization of sweet sorghum bagasse and citric acid in the manufacturing of particleboard. III: influence of adding sucrose on the properties of particleboard [J]. BioResources, 2017, 12(4): 7498−7514. DOI: 10.15376/biores.12.4.7498-7514
|
| [19] |
Li J L, Lei H, Xi X D, et al. A sustainable tannin-citric acid wood adhesive with favorable bonding properties and water resistance [J]. Industrial Crops and Products, 2023, 201: 116933. DOI: 10.1016/j.indcrop.2023.116933
|
| [20] |
Cannatelli M D, Ragauskas A J. Conversion of lignin into value-added materials and chemicals via laccase-assisted copolymerization [J]. Applied Microbiology and Biotechnology, 2016, 100(20): 8685−8691. DOI: 10.1007/s00253-016-7820-1
|
| [21] |
Kong X C, Liu C, Fan Y Y, et al. Depolymerization of methylene linkage in condensed lignin with commercial zeolite in water [J]. ACS Catalysis, 2023, 13(15): 10048−10055. DOI: 10.1021/acscatal.3c02384
|
| [22] |
Sathawong S, Sridach W, Techato K A. Lignin: isolation and preparing the lignin based hydrogel [J]. Journal of Environmental Chemical Engineering, 2018, 6(5): 5879−5888. DOI: 10.1016/j.jece.2018.05.008
|
| [23] |
Xiao X, Jiang J G, Wang Y, et al. Microwave-assisted sulfonation of lignin for the fabrication of a high-performance dye dispersant [J]. ACS Sustainable Chemistry & Engineering, 2021, 9(27): 9053−9061.
|
| [24] |
Xu Q Y, Bai Y Y, Zhao X, et al. Synthesis and characterization of an amphiphilic lignin-based cationic surfactant [J]. Industrial Crops and Products, 2021, 164: 113376. DOI: 10.1016/j.indcrop.2021.113376
|
| [25] |
Larson R A, Sharma B K, Marley K A, et al. Potential antioxidants for biodiesel from a softwood lignin pyrolyzate [J]. Industrial Crops and Products, 2017, 109: 476−482. DOI: 10.1016/j.indcrop.2017.08.053
|
| [26] |
Barana D, Orlandi M, Zoia L, et al. Lignin based functional additives for natural rubber [J]. ACS Sustainable Chemistry & Engineering, 2018, 6(9): 11843−11852.
|
| [27] |
Wei Y X, Song M, Yu L, et al. Preparation of ZnO-loaded lignin-based carbon fiber for the electrocatalytic oxidation of hydroquinone [J]. Catalysts, 2017, 7(6): 180. DOI: 10.3390/catal7060180
|
| [28] |
Li Y T, Jongberg S, Andersen M L, et al. Quinone-induced protein modifications: kinetic preference for reaction of 1, 2-benzoquinones with thiol groups in proteins [J]. Free Radical Biology and Medicine, 2016, 97: 148−157. DOI: 10.1016/j.freeradbiomed.2016.05.019
|
| [29] |
国家市场监督管理总局, 国家标准化管理委员会. 人造板及饰面人造板理化性能试验方法: GB/T 17657—2022[S]. 北京: 中国标准出版社, 2022.
|
| [30] |
Wibowo E S, Kusumah S S, Subyakto, et al. Modification of novel bio-based adhesive made from citric acid and sucrose by ZnCl2 [J]. International Journal of Adhesion and Adhesives, 2021, 108: 102866. DOI: 10.1016/j.ijadhadh.2021.102866
|
| [31] |
Rebollar M, Pérez R, Vidal R. Comparison between oriented strand boards and other wood-based panels for the manufacture of furniture [J]. Materials & Design, 2007, 28(3): 882−888.
|
| [32] |
Wang L D, Li X Q, Gao F, et al. Effects of jet milling pretreatment and esterification with octenyl succinic anhydride on physicochemical properties of corn starch [J]. Foods, 2022, 11(18): 2893. DOI: 10.3390/foods11182893
|
| [33] |
Lin H L, Chen X Y, Lei H, et al. Synthesis and characterization of a bio-aldehyde-based lignin adhesive with desirable water resistance[J]. International Journal of Biological Macromolecules, 2024, 264(Pt 1): 130020.
|
| [34] |
Zhang Y, Wu J Q, Li H, et al. Heat treatment of industrial alkaline lignin and its potential application as an adhesive for green wood–lignin composites [J]. ACS Sustainable Chemistry & Engineering, 2017, 5(8): 7269−7277.
|
| [35] |
Song J X, Chen S, Zhang Q Y, et al. Developing on the well performance and eco-friendly sucrose-based wood adhesive [J]. Industrial Crops and Products, 2023, 194: 116298. DOI: 10.1016/j.indcrop.2023.116298
|
| [36] |
Hao Z T, Xi X D, Hou D F, et al. A fully bio-based soy protein wood adhesive modified by citric acid with high water tolerance[J]. International Journal of Biological Macromolecules, 2023, 253(Pt 6): 127135.
|
| [37] |
国家质量监督检验检疫总局, 中国国家标准化管理委员会. 普通胶合板: GB/T 9846—2015[S]. 北京: 中国标准出版社, 2015.
|
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