王霞, 李浩, 宋永明, 郭蕊, 王清文. 木粉/聚丙烯复合材料的流变性能研究[J]. 西南林业大学学报, 2016, 36(4): 145-151. DOI: 10.11929/j.issn.2095-1914.2016.04.024
引用本文: 王霞, 李浩, 宋永明, 郭蕊, 王清文. 木粉/聚丙烯复合材料的流变性能研究[J]. 西南林业大学学报, 2016, 36(4): 145-151. DOI: 10.11929/j.issn.2095-1914.2016.04.024
Wang Xia, Li Hao, Song Yongming, Guo Rui, Wang Qingwen. Research on Rheological Properties of Wood Flour/Polypropylene Composites[J]. Journal of Southwest Forestry University, 2016, 36(4): 145-151. DOI: 10.11929/j.issn.2095-1914.2016.04.024
Citation: Wang Xia, Li Hao, Song Yongming, Guo Rui, Wang Qingwen. Research on Rheological Properties of Wood Flour/Polypropylene Composites[J]. Journal of Southwest Forestry University, 2016, 36(4): 145-151. DOI: 10.11929/j.issn.2095-1914.2016.04.024

木粉/聚丙烯复合材料的流变性能研究

Research on Rheological Properties of Wood Flour/Polypropylene Composites

  • 摘要: 利用转矩流变仪和旋转流变仪研究了偶联剂、木粉含量及润滑剂对木粉/聚丙烯 (WF/PP) 复合体系加工流动性能和动态流变特性的影响。结果表明:马来酸酐接枝聚丙烯 (MAPP) 偶联剂的添加能够改善木粉和聚丙烯之间的界面结合,使得熔体的平衡转矩和复数黏度升高;随着木粉含量的增加,复合体系的平衡转矩和剪切热增大,线性黏弹性区域减小,储能模量、损耗模量和复数黏度均增大,特征松弛时间延长;硬脂酸的添加,可显著降低复合体系的平衡转矩和剪切热,而且硬脂酸的加入可大幅度降低由木粉含量增加所引起的熔体黏度升高现象,这表明硬脂酸能有效改善高木粉填充体系下,WF/PP复合材料的加工流动性能。

     

    Abstract: The influences of coupling agent, wood flour content and lubricants on the processing flow and dynamic rheological properties of wood flour/polypropylene (WF/PP) composites were investigated through torque and rotational rheometer. Results showed that the addition of maleic anhydride grafted polypropylene (MAPP) improved the interfacial adhesion of wood flour and polypropylene, which increased the equilibrium torque and complex viscosity of WF/PP melts. With the increasing of wood flour content, the equilibrium torque, shear heat, storage modulus, loss modulus, complex viscosity and characteristic relaxation time were increased and the linear viscoelastic region (LVR) was decreased. The addition of stearic acid significantly reduced the equilibrium torque and shear heating of the composite, and the melt viscosity resulted from high wood flour loading was also reduced dramatically. This indicated that stearic acid lubricant effectively improved the processing flow properties of WF/PP melts in the presence of higher wood flour loading.

     

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