刘一楠, 刘珊杉, 郭文静. 木纤维尺寸对聚乳酸结晶特性的影响[J]. 西南林业大学学报, 2017, 37(2): 184-191. DOI: 10.11929/j.issn.2095-1914.2017.02.030
引用本文: 刘一楠, 刘珊杉, 郭文静. 木纤维尺寸对聚乳酸结晶特性的影响[J]. 西南林业大学学报, 2017, 37(2): 184-191. DOI: 10.11929/j.issn.2095-1914.2017.02.030
Yinan Liu, Shanshan Liu, Wenjing Guo. Effects of Wood Fibre Size on Crystallization Morphology of Poly Lactic Acid[J]. Journal of Southwest Forestry University, 2017, 37(2): 184-191. DOI: 10.11929/j.issn.2095-1914.2017.02.030
Citation: Yinan Liu, Shanshan Liu, Wenjing Guo. Effects of Wood Fibre Size on Crystallization Morphology of Poly Lactic Acid[J]. Journal of Southwest Forestry University, 2017, 37(2): 184-191. DOI: 10.11929/j.issn.2095-1914.2017.02.030

木纤维尺寸对聚乳酸结晶特性的影响

Effects of Wood Fibre Size on Crystallization Morphology of Poly Lactic Acid

  • 摘要: 采用混合热压的方法制备不同形态木纤维/PLA复合材料,并通过DSC和POM分析不同形态木纤维与PLA复合对PLA等温和非等温结晶特性的影响。结果表明:木纤维的加入影响了PLA等温结晶的结晶度、结晶速率和熔融温度等特性。中等尺寸木纤维(直径为0.012~0.050 mm,长度为0.3~4.0 mm)能够最有效地增加PLA的结晶度和结晶速率;较大尺寸的木纤维(直径为0.07~0.50 mm,长度为2~10 mm)会阻碍结晶的生长从而降低PLA的结晶度和结晶速率。木纤维复合材料中PLA的熔融温度会随着加入木纤维的尺寸增加而增加;在非等温结晶过程中木纤维会使PLA的结晶度、结晶温度和熔融温度升高,但是尺寸较大的纤维(直径为0.07~0.50 mm,长度为2~10 mm)同样对结晶的生长有很强的阻碍作用,从而降低了PLA的结晶度、结晶温度。POM结果表明,木材纤维会促进PLA的异相成核,并且使PLA在木材纤维表面形成横向结晶层,并且进一步证明了大尺寸的纤维会阻碍结晶生长。

     

    Abstract: The effects of wood fibre (WF) size on isothermal and non-isothermal crystallization morphology and capacity of PLA in WF/PLA composites were investigated with differerntial scanning calorimetry (DSC) and polarising optical microscopy (POM). It was found that wood fibres with different size had different effects on the melting temperature, crystallinity and crystal growth rate of PLA in WF/PLA composites during isothermal crystallization process. The melting peak of PLA component shifted to higher temperature by increasing fibre size. The middle size WF (diameter=0.012-0.050 mm, length =0.3-4.0 mm) could promote heterogeneous nucleation of PLA, increased crystal growth rate and crystallinity of PLA in composites. But the large size WF (diameter=0.07-0.50 mm, length=2-10 mm) would hinder crystal growth, then reduce crystallinity. On non-isothermal crystallization phase the results show that proper WF size could increase the overall crystallinity, melting peak temperature and crystallization temperature. But the large size WF (diameter=0.07-0.50 mm, length=2-10 mm) is too big to promote crystal growth. POM shows WF as a sort of heterogeneous nucleating agent could promote nucleus forming at the WF surface and confirmed the large WF would hinder crystal growth.

     

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