王辉, 王洪艳, 普龙, 黄兴, 杜官本. 氧化木薯淀粉用量对脲醛树脂性能的影响[J]. 西南林业大学学报, 2018, 38(1): 175-179. DOI: 10.11929/j.issn.2095-1914.2018.01.027
引用本文: 王辉, 王洪艳, 普龙, 黄兴, 杜官本. 氧化木薯淀粉用量对脲醛树脂性能的影响[J]. 西南林业大学学报, 2018, 38(1): 175-179. DOI: 10.11929/j.issn.2095-1914.2018.01.027
Hui Wang, Hongyan Wang, Long Pu, Xing Huang, Guanben Du. Effects of Oxidation Cassava Starch Content on Urea-formaldehyde Resin Performance[J]. Journal of Southwest Forestry University, 2018, 38(1): 175-179. DOI: 10.11929/j.issn.2095-1914.2018.01.027
Citation: Hui Wang, Hongyan Wang, Long Pu, Xing Huang, Guanben Du. Effects of Oxidation Cassava Starch Content on Urea-formaldehyde Resin Performance[J]. Journal of Southwest Forestry University, 2018, 38(1): 175-179. DOI: 10.11929/j.issn.2095-1914.2018.01.027

氧化木薯淀粉用量对脲醛树脂性能的影响

Effects of Oxidation Cassava Starch Content on Urea-formaldehyde Resin Performance

  • 摘要: 通过调节甲醛、尿素用量,控制脲醛树脂的物质的量比为1.0和1.5,并在脲醛树脂合成反应后期,加入不同比例的氧化木薯淀粉进行改性,考察不同氧化木薯淀粉添加量对不同物质的量比脲醛树脂基本性能、固化特征以及胶接性能的影响。结果表明:氧化木薯淀粉可以有效提升脲醛树脂的固体含量及粘度,而对树脂固化特征的影响随nF : nU和添加量的不同而表现不一;当nF : nU=1.0时,随着氧化木薯淀粉用量的增加,树脂的固化时间在逐渐缩短,用量在5%以内时,树脂的固化起始温度均低于未改性树脂,湿状胶接强度先增后降;当nF : nU=1.5时,树脂固化时间变化趋势同前,但固化起始温度均高于未改性树脂,干、湿状胶接强度随氧化淀粉用量的增加而提高;从树脂的综合性能考虑,nF : nU=1.0时,氧化木薯淀粉用量为尿素用量的3%时,综合效果最优,而nF : nU=1.5时,5%时综合效果最优。

     

    Abstract: Two kinds of urea-formaldehyde resin was synthesized with F : U molar ratio 1.0 and 1.5, to which different oxidation cassava starch content was added at the end of reaction period. The basic performance, curing characteristics and glued strength of resins were studied. The results showed that oxidation cassava starch could increase the solid content and viscosity of resins, but the curing characteristic obviously changed with different F : U molar ratio and oxidation cassava starch content. When nF : nU=1.0, resin curing time was shorted by increasing oxidation cassava starch content. Within 5% cassava starch content, the initial curing temperature was lower compared with pure UF, the wet strength of plywood was first increased then down. When nF : nU=1.5, the curing time changed as the nF : nU=1.0, while the initial curing temperature was all higher than pure UF, thus the dry and wet strength were increased with the increase of oxidation cassava starch usage. At last, by considering integrated performance of resin, when nF : nU=1.0, the mass ratio of oxidation cassava starch and urea was 3%, the resin performance was the best. And when nF : nU=1.5, mass ratio of that was 5% was the best.

     

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