周晓剑, 王文丽, 李斌, 孙蓉莹, 李喆, 杜官本. 超支化聚合物改性三聚氰胺甲醛树脂的物理性能研究[J]. 西南林业大学学报, 2018, 38(6): 166-171. DOI: 10.11929/j.issn.2095-1914.2018.06.022
引用本文: 周晓剑, 王文丽, 李斌, 孙蓉莹, 李喆, 杜官本. 超支化聚合物改性三聚氰胺甲醛树脂的物理性能研究[J]. 西南林业大学学报, 2018, 38(6): 166-171. DOI: 10.11929/j.issn.2095-1914.2018.06.022
Xiaojian Zhou, Wenli Wang, Bin Li, Rongying Sun, Zhe Li, Guanben Du. The Physical Properties of Melamine-Formaldehyde Resin Modified with Hyperbranch Polymers[J]. Journal of Southwest Forestry University, 2018, 38(6): 166-171. DOI: 10.11929/j.issn.2095-1914.2018.06.022
Citation: Xiaojian Zhou, Wenli Wang, Bin Li, Rongying Sun, Zhe Li, Guanben Du. The Physical Properties of Melamine-Formaldehyde Resin Modified with Hyperbranch Polymers[J]. Journal of Southwest Forestry University, 2018, 38(6): 166-171. DOI: 10.11929/j.issn.2095-1914.2018.06.022

超支化聚合物改性三聚氰胺甲醛树脂的物理性能研究

The Physical Properties of Melamine-Formaldehyde Resin Modified with Hyperbranch Polymers

  • 摘要: 利用超支化聚合物聚酰胺-胺(PAMAMs)对三聚氰胺甲醛树脂(MF)进行共混改性, 并用改性前后的MF树脂完成浸渍胶膜纸和饰面装饰板的制备, 从物理性能方面分别对树脂、浸渍胶膜纸和饰面板进行表征研究。结果表明:PAMAMs的加入降低了MF树脂胶黏剂的粘度, 缩短了固化时间和延长其贮存期; PAMAMs的加入使树脂浸渍纸的抗张强度提高43%和抗伸长率提高100%;改性树脂浸渍纸饰面板的物理性能分析得出, 饰面板的表面耐污渍、表面耐磨和抗拉强度等方面均得到明显提升。

     

    Abstract: To investigate the blending modification of melamine-formaldehyde (MF) resins using hyperbranched polymer polyamidoamines (PAMAMs), and the preparation of impregnated paper and veneer-faced decorative boards using MF resins before and after modification. In respects of physical properties, resins, impregnated paper and decorative boards were characterized, respectively. The results showed that PAMAMs reduced the viscosity of MF resin adhesives, shortened curing time and significantly prolonged storage period. In addition, PAMAMs increased the tensile strength and elongation resistance of resin-impregnated paper by 43% and 100%, respectively. Physical property analysis of decorative boards with modified resin-impregnated paper demonstrated that the surface of decorative boards was more resistant to stains, steam cycle and wear, and surface tensile strength was improved significantly.

     

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