基于LF-NMR及MRI 的2种速生材干燥过程中水分分布状态研究

Study on Water Status and Distribution in 2 Fast-growing Woods During Drying Based on LF-NMR and MRI

  • 摘要: 为了解太阳能干燥过程中速生材内部水分状态及迁移规律,采用低场核磁共振及核磁共振成像检测桉、杨木干燥过程中水分分布、含量变化及迁移过程,借助扫描电镜在微观层面进行分析。结果表明:核磁共振信号强度与称重法所测含水率相关性系数高达0.99以上,因此低场核磁共振可准确测定木材中的水分含量;桉木和杨木饱水试样的核磁共振信号中均存在3种峰,桉木弛豫时间分别为1.32、32.75、403.70 ms,杨木为2.66、32.75、352.12 ms,对应着结合水及两种状态的自由水;随着干燥进行,不同状态水分的横向弛豫时间逐渐减小,木材对水分的束缚增加。当桉木含水率为27.28%,杨木含水率为35.71%左右时,水分散失转为以结合水为主。通过核磁共振成像中氢质子密度的不同可对水分含量进行区分,进而可观测干燥过程中木材内部水分移动状态。因此,通过低场核磁共振及核磁共振成像可研究速生材干燥过程中的内部水分状态及分布。

     

    Abstract: In order to throw a light on the moisture state and migration in fast-growing wood during solar drying process, low field nuclear magnetic resonance (NMR) and magnetic resonance imaging (MRI) were used to detect the moisture distribution, content change and its migration of Eucalyptus robusta and Populus tomentosa wood during the drying, and the scanning electron microscope (SEM) was used for the microscopic analysis. The results showed that the nuclear magnetic resonance (NMR) signal quantity was linearly correlated with the water content measured by weighing method, and the correlation was up to 0.99, making it possible for obaining the water content of wood in drying process via the equation constructed. According to the relaxation distribution of wood, there were 3 peaks in both Eucalyptus and Poplars during drying, including bound water and free water in 2 states, the relaxation time were 1.32, 32.75 ms, and 403.70 ms for the Eucalyptus and 2.66, 32.75 ms, and 352.12 ms for the Poplars, respectively. As the drying progresses, the relaxation time of water in different states decreased gradually, and the binding of wood to water increased. When the moisture content of the Eucalyptus and Poplars was about 27.28% and 35.71%, the loss of water was mainly composed of bound water. The moisture content could be distinguished by the density of hydrogen proton in magnetic resonance imaging (MRI), and the moisture movement in wood during drying could be observed. Therefore, the moisture states and distribution in wood can be quantitatively obtained by the LF-NMR and MRI.

     

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