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木基玄武岩纤维复合材料制备及性能评价
Preparation and performance evaluation of wood-based basalt fiber composites
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摘要: 采用NaOH、HCl和KH550对玄武岩纤维进行预处理,提高其界面性能,再与木单板复合热压成复合材料。以预处理试剂种类、加入量和处理时间为影响因素,采用正交实验方法,分析各因素对其界面胶合性能的影响;通过接触角、扫描电镜和傅立叶红外光谱验证界面胶合改性机理。预处理后的玄武岩纤维布与木单板复合,通过胶合强度、力学性能和阻燃性能对其进行性能评价。结果表明:质量分数为3%的KH550处理玄武岩纤维布1 h的效果最好,使用35%固含量的酚醛树脂胶黏剂对其涂饰压制的复合板材与对照材料相比,胶合强度达到1.73 MPa,横纵向的静曲强度分别提高了25.6%和21.3%,弹性模量分别提高了13.1%和17.5%;通过燃烧现象和失重率分析,木基玄武岩纤维复合板材的上下燃烧面积较对照材料小很多,且燃烧相同时间,其质量损失率分别为4.60%和9.86%。木基玄武岩纤维复合材料的胶合性能、力学性能和阻燃性能相较于普通胶合板均有较大程度的改善。Abstract: Basalt fibers were pretreated with NaOH, HCL and KH550 to improve their interfacial properties, and then laminated with wood veneer and hot-pressed into composites.. Taking the pretreatment reagent type, addition amount and treatment time as the influencing factors, orthogonal experimental methods were used to analyze the influence of each factor on its interfacial adhesive properties; the interfacial adhesive modification mechanism was verified by contact angle, scanning electron microscopy and Fourier infrared spectroscopy. The pretreated basalt fiber cloth was laminated with wood veneer, and its performance was evaluated by gluing strength, mechanical properties and flame retardant properties. The results showed that KH550 with a mass fraction of 3% had the best effect in treating the basalt fiber cloth for 1 h. Compared with the control material, the glued strength of the pressed composite boards coated with phenolic resin adhesive with 35% solid content reached 1.73 MPa, the static bending strength in the transverse and longitudinal directions were increased by 25.6% and 21.3%, and the modulus of elasticity was increased by 13.1% and 17.5%, respectively; Through the analysis of combustion phenomenon and weight loss rate, the upper and lower combustion area of wood-based basalt fiber composite panels is much smaller than that of the control material, and burning for the same time, its mass loss rate is 4.60% and 9.86%, respectively. the gluing properties, mechanical properties and flame retardant properties of wood-based basalt fiber composite materials are improved to a greater extent compared with ordinary plywood.