脱脂紫茎泽兰水凝胶的制备研究

Hydrogel Preparation Technology with Degreased Eupatorium adenophorum

  • 摘要: 以苯-醇溶液脱脂后的粉末状紫茎泽兰为初始原料,优化制备廉价且具有高吸液性能的农林用保水水凝胶。结果表明:丙烯酸和丙烯酰胺2种单体总量与原料质量比为11∶1,丙烯酸中和度45%,引发剂用量占原料质量的1.5%,交联剂用量占总单体量的04%,反应温度60 ℃,时间5 h,制得水凝胶吸液性能较优;在去离子水和09%NaCl溶液中,凝胶最大饱和溶胀度分别为931g/g和337g/g。用傅立叶红外光谱(FT-IR)证明原料成功接枝聚丙烯酸和聚丙烯酰胺单体,通过扫描电镜(SEM)对产物表面形态进行表征。

     

    Abstract: The lowcost superabsorbent hydrogel for agriculture and forestry was manufactured by taking the pulverized Eupatorium adenophorum as raw material that was degreased by benzeneethanol mixture. The results showed that the hydrogel with optimal absorbency was obtained under the conditions that the weight ratio of AA/AM graft copolymerization to dry pulverized raw material as 11∶1, the neutralization degree of AA as 45%, the weight ratio of initiator to raw material as 0015∶1.000, the weight ratio of crosslinker to two monomers as 0004∶1.000, the reaction was taken place at 60 ℃ for 5 h. The maximum saturated swelling degree of the hydrogel was 931 g/g in deionized water and 337 g/g in 09% NaCl solution. The evidence of graft copolymerization was determined by using FT-IR spectroscopy, and the surface morphology of the PAA/PAM hydrogel product was characterized by SEM.

     

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